2-Chloro-1,2-diphenylethanone (desyl chloride)

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2-Chloro-1,2-diphenyl­ethanone (desyl chloride)

The title compound, C(14)H(11)ClO, is a racemic derivative of benzoin. Its carbonyl group adopts a nearly eclipsed conformation with the Cl substituent characterized by a dihedral angle of 17.5 (2)°. The closest intermolecular π-π contact is 4.258 (1) Å.

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3-Chloro-2-methyl­anilinium chloride monohydrate

In the title hydrated salt, C7H9ClN(+)·Cl(-)·H2O, the organic cations, anions and water mol-ecules are connected by N-H⋯Cl, N-H⋯O and O-H⋯Cl hydrogen bonds. These inter-actions lead to the formation of layers parallel to the ac plane.

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7-Chloro-4-(2-hy­droxy­ethyl­amino)­quinolin-1-ium chloride

In the title salt, C11H12ClN2O(+)·Cl(-), the ten non-H atoms comprising the quinolinium residue are coplanar (r.m.s. deviation = 0.041 Å) and the hy-droxy-ethyl group is approximately perpendicular to this plane [Cring-N-Cmethyl-ene-C torsion angle = -74.61 (18)°]. A supra-molecular chain aligned along [101] mediated by charge-assisted O/N-H⋯Cl(-) hydrogen bonds features in the crystal packing....

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2-Chloro-12-phenyl-6,7,8,9,10,11-hexa­hydro­cyclo­octa­[b]quinoline

In the mol-ecule of the title compound, C(21)H(20)ClN, the quinoline group is nearly planar and is oriented at a dihedral angle of 77.21 (3)° with respect to the phenyl ring. The conformation of the cyclooctane ring is twist-boat. In the crystal structure, there are some weak π-π inter-actions [centroid-to-centroid distances of 3.7414 (11) and 3.8633 (12) Å] between the rings of the quinoline g...

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Crystal structure of chloro(2,2':6',2"-terpyridine)(2-phenylazopyridine)-ruthenium(II) chloride.

complexes (where tpy = 2,2′:6′,2′′-terpyridine, L = bidentate ligand, n = 0 or 1), because they are used as precursors of aquo complexes, which can finally be converted to oxo compounds. Oxo-ruthenium complexes are useful as catalysts in different reactions, particularly in the catalytic oxidation of water to dioxygen.1,2 As a part of serial studies on the properties of oxoruthenium complexes, ...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811014541